Fluorination of the chlorohydrocarbon is substitution nucleophilic unimolecular. This fluorinated reaction is decided by the stability of intermediate R+. 氯代烃的氟化是单分子亲核取代反应,其氟化反应的进程决定于中间体R+稳定性。
The results obtained show that these compounds undergo unimolecular first-order pyrolytic reaction via a six-center cyclic transition state. This kind of the reaction is controlled by migrating of the atom H 17 with positive charge. 结果表明反应是一个H17带正电迁移引发的途经六元环过渡态的单分子热消除反应。
Coherent Laser Control over the Unimolecular Reaction of CH_3I 激光相干控制CH3I单分子反应的实验研究
The mechanisms of the hydrolysis were proposed to be unimolecular nucleophilic substitution and bimolecular nucleophilic substitution ( SN2). On the Problem of Bimolecular Nucleophilic Substitution Reaction Sterochemistry 水解反应的可能机理是SNl和SN2.双分子亲核取代反应立体化学问题释疑
The unimolecular reaction of CF_2HCl dissociation on platinum black has been studied. At higher pressure, this reaction is zero order, while at lower pressure, it I first order. It implies that the reaction is a typical catalytic reaction. 本文研究了CF2HCl在铂黑表面上的单分子反应,在压力较高时为零级,压力较低时为一级,表明此反应为典型的催化反应。
A mechanism including both unimolecular and chain reaction channel has been proposed for the decomposition of 1,2& dichloropropane. 本研究证实了链式通道的存在,阐明了1,2&二氯丙烷分解反应中单分子反应通道和链式反应通道共存的反应机理。
Kinetics of unimolecular reaction of cf_2hcl on W surface CF2HCI在金属钨表面上的反应动力学
A Computer Program for Tunneling in Unimolecular Thermal Reaction System in Chemical Kinetics-KANDE 化学动力学中单分子热反应隧道效应计算程序KANDE
Study on Tunneling Effect in the Chemical Kinetics I. Study on Tunneling in Thermal Unimolecular Reaction of Formaldehyde 化学动力学中隧道效应的研究Ⅰ.甲醛单分子热反应中隧道效应的研究